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Krypton is used in flashlight bulbs. |
Krypton
| Atomic Number: | 36 | Atomic Radius: | 202 pm (Van der Waals) |
| Atomic Symbol: | Kr | Melting Point: | -157.37 °C |
| Atomic Weight: | 83.79 | Boiling Point: | 153.415°C |
| Electron Configuration: | [Ar]4s23d104p6 | Oxidation States: | 2, 1, 0 (rarely more than 0; unknown oxide) |
History
From the Greek word kryptos, hidden. Discovered in 1898 by Ramsay and Travers in the residue left after liquid air had nearly boiled away. In 1960 it was internationally agreed that the fundamental unit of length, the meter, should be defined in terms of the orange-red spectral line of 86Kr. This replaced the standard meter of Paris, which was defined in terms of a bar made of a platinum-iridium alloy. In October 1983, the meter, which originally was defined as being one ten millionth of a quadrant of the earth's polar circumference, was again redefined by the International Bureau of Weights and Measures as being the length of a path traveled by light in a vacuum during a time interval of 1/299,792,458 of a second.
Sources
Krypton is present in the air to the extent of about 1 ppm. The atmosphere of Mars has been found to contain 0.3 ppm of krypton. Solid krypton is a white crystalline substance with a face-centered cubic structure which is common to all the "rare gases."
Properties
Krypton is a "noble" gas. It is characterized by its brilliant green and orange spectral lines.
Isotopes
Naturally occurring krypton contains six stable isotopes. Seventeen other unstable isotopes are recognized. The spectral lines of krypton are easily produced and some are very sharp. While krypton is generally thought of as a rare gas that normally does not combine with other elements to form compounds, it now appears that the existence of some krypton compounds can exist. Krypton difluoride has been prepared in gram quantities and can be made by several methods. A higher fluoride of krypton and a salt of an oxyacid of krypton also have been reported. Molecule-ions of ArKr+ and KrH+ have been identified and investigated, and evidence is provided for the formation of KrXe or KrXe+.
Uses
Krypton clathrates are prepared using hydroquinone and phenol. 85Kr can be used for chemical analysis by imbedding the isotope in various solids. During this process, kryptonates are formed. Kryptonate activity is sensitive to chemical reactions at the solution surface. Estimates of the concentration of reactants are therefore made possible. Krypton is used in certain photographic flash lamps for high-speed photography.